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Specifically, examples include programmed photoactive molecular architectures binding cations, anions and H-bonded neutral guests. In these systems the non-covalent molecular recognition adds onto the thermal and light stimuli, equipping the supramolecular architecture with an additional external trigger to select the desired configuration composition. © 2020 The Authors. Published by Wiley-VCH Verlag GmbH Co. KGaA.Two new families of N,O-nucleoside analogues containing the anthracene moiety introduced through the n