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The optimized products, black-coloured NaTaO(3-x)N(y), exhibit desirable band gap down to 2.2 eV and excellent photocatalytic activity for the degradation of organic pollutants under visible light irradiation. More importantly, our approach for preparing Ta(4+)/N co-doped NaTaO3 provides a good example for the combination of controllable syntheses routes and chemical doping methods to promote traditional wide-band catalysts for visible-light driven applications.Multi-length scale porous polymer (MLSPP) films were fabricated using commerc