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Selective oxidation of amine to imine using sunlight as clean and renewable energy source is an important but challenging chemical transformation due to high reactivity of generated imines and lack of visible light responsive materials with high conversion rates. In addition, oxygen gas has to be purged in the reaction mixture in order to increase the reaction efficiency which, in itself, is an energy consuming process. Herein, we report for the first time the use of Ag3PO4 as an excellent photocatalyst for the oxidative coupling of be