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We now have exploited our recently reported solid-state topochemical polymerization/cyclization-aromatization technique to convert the simple 1,4-bis(3-pyridyl)butadiynes 3a,b into the fjord-edge nitrogen-doped graphene nanoribbon frameworks 1a,b (fjord-edge N2[8]GNRs). Architectural assignments tend to be verified by CP/MAS 13C NMR, Raman, and XPS spectroscopy. The fjord-edge N2[8]GNRs 1a,b are promising precursors for the novel backbone nitrogen-substituted N2[8]AGNR