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g., high carrier flexibility, large photoconductivity, and thermoelectric reaction). The outstanding semiconducting properties of group-VI elemental 2D products enable device programs including high-performance field-effect transistors and optoelectronic devices. The excellent ecological security also facilitates fundamental studies and useful applications of group-VI elemental 2D products. This Review very first focuses on the crystal structures of group-VI elemental 2D products. Later, pla
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