https://ttnpbagonist.com/posto....perative-serious-glu
Every one of the RhI carbonyl buildings in both ylide series were fully characterized, including through X-ray diffraction evaluation. In line with the experimental and calculated infrared (IR) CO stretching frequencies in Rh(CO)2 complexes, we evidenced that the phosphonium ylide ligand is a stronger donor compared to the iminophosphorane ligand. But, we also found that the difference in the intrinsic electric properties can be mostly paid because of the introduction of an