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The substances had been synthesized using a modified Pechini method. Sophistication for the synchrotron X-ray diffraction (S-XRD) information showed that the examples had an orthorhombic Pbnm symmetry. The incorporation of Eu in to the lattice led to increased short- and long-range disorder, inducing extra distortion within the SnO6. XANES measurements uncovered that mixed Eu valences (Eu3+ and Eu2+) were present in Eu-doped samples, and DFT calculations confirmed the clear presence of thes