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g., Li-ion/S and Li-ion/O2 batteries) and high power-density Li-ion capacitors (LICs). The related progress is also summarized. Finally, perspectives are suggested on the future trend of prelithiation techniques to propel the commercialization of advanced LIBs/LICs.A hierarchically ordered porous carbon electrocatalyst with exclusively surface-anchored cobalt species, dubbed Co@HOPC, is synthesized from polyaniline and cobalt-functionalized silica microparticles templates, and its high electrocatalytic activity for the oxygen evolution