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Combinatorial syntheses of such libraries need water- and DNA-compatible responses, and also the paucity of the responses presently reduce chemical features of resulting barcoded products. The current work introduces strain-promoted cycloadditions of cyclic allenes under moderate circumstances to DNA-encoded library synthesis. Due to distinct cycloaddition modes of those reactive intermediates with activated olefins, 1,3-dipoles, and dienes, the process creates diverse molecular architectur
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