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This method provides a route for the resource utilization of spent LIBs and the synthesis of MnO2.Adsorption is an important technology to deal with volatile organic compounds (VOCs), and biochar has attracted much attention as a new type of adsorbent for VOCs. In this study, rice husk, corn stover and pine wood sawdust biochars from different pyrolysis temperatures (300 °C, 500 °C and 700 °C) were synthesized and treated by ball milling. The pristine and ball-milled biochars were used as adsorbents for acetone and toluene removal. Resu