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To explore a green, low-cost, and efficient strategy to synthesis reduced graphene oxide (RGO), the process and mechanism of the graphene oxide (GO) reduction by a model electrochemically active bacteria (EA, Geobacter sulfurreducens PCA, were studied. In this work, up to 1.0 mg mL-1 of GO was reduced by G. sulfurreducens within 0.5-8 days. ID/IG ratio in reduced product was similar to chemically RGO. After microbial reduction, the peak which corresponded to the reflection of graphene oxide (001) disappeared, while another peak consi