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Five natural linkers are examined in conjunction with lithium terephthalic acid (TPA), 3,5-pyridinedicarboxylic acid (PDC), 2,6-naphthalenedicarboxylic acid (NDC), 4,4'-biphenyldicarboxylic acid (BPDC), and 4,4'-azobenzenedicarboxylic acid (AZO). In particular, the electrochemical activity of Li-PDC in addition to crystal framework of Li-AZO are dealt with here for the first time. We believe the inside situ gas-phase thin-film deposition is an important necessity to profit from the iMOF-type elect