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This paper investigates the relationship between yield of carbon nanostructures produced in flame environment and flue gas emissions for an axisymmetric co-flow diffusion flame. Simulation has been carried out at four different equivalence ratios to scrutinize the optimum ratio at which maximum carbon nanostructures can be obtained with minimum hazardous emissions. Numerical model solves the time-independent Navier-Stokes equation coupled with the equations for energy and species conservation to compute the temperature and species dist