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e., X- + 3O3 → XO3- + 3O2) aided by the first addition representing the price deciding action. Evidence can also be provided for (i) slow reverse reactions of XO- and XO2-, not XO3-, with molecular oxygen and (ii) the photodissociation of IO-, IO2- and IO3- to discharge I-. Collectively, these results recommend relatively brief lifetimes for Br- and I- within the tropospere with direct gas-phase oxidation by ozone playing a job both in the forming of atmospheric halogen oxides and, conversely, within the ozone exhaustion connected with