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As for hydrochar with more O-containing functional groups than biochar, the dominated sorption mechanism would be surface complexation, due to higher sorption capacity of Aged-HC with richer O-containing functional groups. In binary-metal system, the competitive sorption of Cd(II) and Cu(II) on biochar was observed obviously but that on hydrochar was limited. Ageing could increase the sorption capacity of Cd(II) in binary-metal system, resulting in alleviating competitive adsorption. The total sorption amount of Cd(II) and Cu(II) by bioc