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How to rapidly and efficiently separate surfactant-stabilized emulsions has been a great challenge for oil/water separation materials. In this work, a durable superwetting copper mesh with high efficiency and flux for gravity-driven emulsion separation was fabricated by subtly inlaying polydopamine/polyethyleneimine@aminated carbon nanotubes (PDA/PEI@CNTs-NH2) clusters in the mesh pores. The porous clusters with abundant cationic groups render the mesh with superwettability, submicron permeation channels and positive charges, so as to