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Defects caused by the nonstoichiometric synthesis created microstrain within the host CCO, resulting in making the new density of states near the Fermi energy. Further, the exsolution process turned the inert host (CCO) into electrocatalytically active toward water splitting. The nonstoichiometric samples obtained by shorter annealing times showed high electrocatalytic behavior for the hydrogen evolution (HER) and oxygen evolution (OER) reactions. The catalytic activity is further enhanced (reaching overpotential of 320 mV and 410 mV for H