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This review will help researchers to obtain a better understanding of development of superior MoS2 HER electrocatalysts, providing directions for next-generation catalyst development.Metal closo-borates and their derivatives have shown promise in several fields of application from cancer therapy to solid-state electrolytes partly owing to their stability in aqueous solutions and high thermal stability. We report the synthesis and structural analysis of α- and β-CaB10H10, which are structurally and energetically similar, both showing a