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Nanostructured metallic glass films (NMGF) can exhibit surface and intrinsic effects that give rise to unique physical and chemical properties. Here we report a facile synthesis and electrochemical, structural, and morphologic characterization of Pd-Au-Si based MGs of ~50 nm thickness supported on Si/SiO2 . Impressively, the maximum total hydrogen charge stored in Pd-Au-Si nanofilm is equal to that in polycrystalline Pd films with thickness in 0.1 M H2SO4 electrolyte. The same NMGF has a volumetric desorption charge that is more than ei