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The CdS/g-C3N4 hybrid was prepared mechanically and characterized by different techniques including XRD, SEM, DRS, FTIR, and cyclic voltammetry (CV). The SEM study showed that CdS nanoparticles (NPs) have been randomly dispersed on the surface of graphitic carbon nitride (g-C3N4). The CV results showed better charge carriers' transfer for the modified carbon paste electrode (CPE) by the CdS/g-C3N4 system concerning the modified CPE by single CdS or g-C3N4 modifier. The band gap (Bg) energies of 1.7, 2.7, and 1.9 eV were obtained from DRS