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Co3+ doping in BiFeO3 is expected to be an effective method for improving its magnetic properties. In this work, pristine BiFeO3 (BFO) and doped BiFe1-xCoxO3 (BFCxO, x = 0.01, 0.03, 0.05, 0.07 and 0.1 composite thin films were successfully synthesized by a sol-gel technique. XRD and Raman spectra indicate that the Co3+ ions are substituted for the Fe3+ ion sites in the BFO rhombohedral lattice. Raman vibration of oxygen octahedron is obviously weakened due to the lattice distortion induced by the size mismatch between two B-site catio