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Our findings suggest the effective way to suppress MIGS by an introduction of the clean Gr interlayer, which paves the way to study intrinsic electrical properties of various materials.A highly photoluminescent material was obtained by the incorporation of perylene into an inorganic-organic hybrid film. Octosilicate, a layered alkali silicate, was modified with a cationic surfactant, dioleyldimethylammonium ion, to accommodate perylene molecularly and uniformly. The perylene-doped dioleyldimethylammonium octosilicate films were fabrica