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Herein, we measured the HER, OER, and ORR activities of Aun(SR)m and alloy clusters containing different variety of constituent atoms, ligand functional groups, and heteroatom species under identical experimental circumstances. We received a comprehensive group of results that illustrates the effect of each and every parameter from the tasks associated with three reactions. Comparison of the a number of outcomes disclosed that lowering how many constituent atoms within the cluster, redu