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The core-shell UiO-67@Ni-MOF composites were synthesized by internal prolonged development of layer Ni-MOF from the core UiO-67 under polyvinylpyrrolidone (PVP) regulation. In the sensor system, UiO-67 with large particular surface and great conductivity had been used to speed up the price of electron transfer of UiO-67@Ni-MOF. Ni-MOF served as an electrocatalytic product as a result of exemplary electrochemical task toward glucose oxidation. The morphology, construction, and electrochemical performance