https://www.selleckchem.com/Androgen-Receptor.html
Hydrazones are common carbene precursors in many palladium-catalyzed cross coupling reactions of carbenes as a coupling partner, but their interaction with palladium has been overlooked. We have found that hydrazonato ligands readily coordinate to Pd aryl complexes leading to [PdAr(L-L)(TolSO2)N-NCHR] (Ar = Ph, C6F5; L-L = dppe, dppf; R = CHCHPh, Ph). Ligand substitution reactions on [PdAr(dppe)X] (X = Br, TolSO2) show that the hydrazonato ligand coordinates preferentially so the hydrazonato complexes are likely resting states in cat
Like
Comment
Share
