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When waves are incident from a high-index medium to a low one, total reflection occurs commonly for the incidence beyond the critical angle. However, this common sense is broken by a purely imaginary metamaterial (PIM), which also supports a real refraction index yet with pure loss and gain elements in their permittivity and permeability. We find that even beyond the critical angle of a lower-index PIM slab, some extraordinary wave modes including laser, anti-laser, perfect attenuator and perfect amplifier can appear. The general conditi