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At the mole ratio of NH4+ As = 81 and Mg2+ As = 1.51, 96.38% of arsenic was removed, and the content of arsenic in the arsenic slag composed of MgNH4AsO4·6H2O reached 28.96%. On this basis, the circulating alkali leaching of copper smelter dust based on arsenic-alkali separation was successfully carried out. The whole scheme is not only economical and safe, but also achieves the reuse of wastewater without secondary pollution, which provides an alternative solution for the treatment of arsenic containing solid waste.In the present stu