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Incorporation of dual functions, i.e., sensing and adsorption, into one single organic-inorganic hybrid material for the detection and removal of toxic permanganate (MnO4-) ions is of great importance, representing a challenging and new task in the design and application of new functional materials. However, most of the reported materials display only one function as either sensing probes or adsorbents. In this work, a fluorescent cuboid mesoporous silica-based hybrid material (SiO2@SFNO) is first prepared by the covalent coupling of a n