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We demonstrate that the underwater superpolymphobic SSM can be effectively and repeatedly used to separate liquid polymer/water mixtures with a high separation efficiency of 99.0% and a high separation flux of 4.45 × 105 L m-2h-1. The mixtures of water and different polymers are successfully separated. Such a separation strategy can potentially alleviate pollution from liquid polymer discharge, recycle waste polymer resources, and be applied in polymer production and manufacturing.The specific binding of fluorescent probes or biomolecu