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This application-oriented rational design protocol can be potentially used to extend toward high performance composite membranes derived from other electro-conductive metal substrates functionally decorated with CNT network and to other applications in water treatment.BES biogas upgrading studies have typically used bicarbonate or commercial gas mixtures as a biocathode substrate instead of anaerobic digester biogas. Therefore, the objective of this study was to (i) compare the performance of a methanogenic BES between CO2-fed and biog