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To overcome this matter, a fresh narrow bandgap NFA TT-S-4F is reported by exposing 3,6-dimethoxylthieno[3,2-b]thiophene (TT) as π-spacers to connect electron-rich core with terminal teams, in order to upshift the LUMO degree and increase π-system. When including 10% TT-S-4F into binary system predicated on PTB7-ThIEICO-4F, the higher-LUMO-level of TT-S-4F, the enhanced charge mobilities, the decreased trap-assisted combination reduction, and a finer nanofiber framework and increased p
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