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We additionally demonstrate preparation and measurement of maximally entangled 171Yb-51V Bell states. Unlike conventional, disordered nuclear-spin-based quantum memories16-24, our platform is deterministic and reproducible, ensuring identical quantum registers for all 171Yb3+ qubits. Our approach provides a framework for utilizing the complex structure of dense nuclear spin baths, paving the way towards building large-scale quantum networks using single rare-earth ion qubits15,25-28.Night-time provides a critical window for slowing or ex