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2 V at a current density of 15 mA g-1. The parent Na0.7MnO2 is compared with alkali metal (K, Rb, and Cs)-modified Na x MnO2 in terms of surface morphology using scanning transmission electron microscopy coupled with energy-dispersive X-ray spectroscopy, scanning electron microscopy, 23Na solid-state nuclear magnetic resonance, and X-ray photoelectron spectroscopy and in terms of electrochemical performance and structural electrochemical evolution using in situ or operando synchrotron X-ray diffraction.Computational simulation of nonadiabatic molecular dyna