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, air as an oxidant, room temperature, and involving no photosensitizer or cocatalyst.Gradiented sulfonation ended up being carried out for the area customization of cellulose nanocrystals by conjugate addition with sodium vinyl sulfonate moieties. The self-assembly behaviors associated with the changed nanocrystals in the liquid state as suspensions as well as in the solid state as movies had been regulated by their particular surface chemistry and crystalline properties.We report single yttrium