https://www.selleckchem.com/pr....oducts/17-DMAG,Hydro
In the presence of PMe3, Cii) complexes κ2C,N-R[NCN]CoBr(PMe3)2 (3a-d) and a bisligated cobalt(ii) complex κ3N,C,N-κ2C,N-iPr[NCN]2CoPMe3 (4d) can be prepared respectively in high yields. The molecular structures of 1d-LiBr, 1d-CoCl2, 2b, 2d, 3a, and 4d were confirmed by X-ray crystallographic analysis and the detailed mechanisms of the disproportionation reaction were proposed.The interfacial co-existence of oxygen and metal vacancies in metal oxide semiconductors and their highly efficient carrier transport have ra