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Finally, feed step-increases also increased some amino acid derivatives used in cell-signalling. Interestingly, some natural products from plant and fungal extracts were also found in the fourth compartment, where methanogenesis was the dominant process. In this study, water treatment residuals (WTRs), a safe and valuable by-product containing iron, was used as a precursor for preparing effective activator (HWTRs) of peroxymonosulfate (PMS) for imidacloprid (IMD) degradation by hydrothermal treatment. Several affecting parameters on IM