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One ring threaded by two other bands to form a non-intertwined ternary ring-in-rings theme is a challenging task in noncovalent synthesis. Making multicolor photoluminescence methods with tunable properties can also be significant research objective, that may cause applications in multidimensional biological imaging, aesthetic displays, and encryption materials. Herein, we describe the look and synthesis of binary and ternary ring-in-ring(s) buildings, based on a prolonged tetracationic cycloph