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These results proved that M-gallate pellets was promising candidates for the practical industrial realization of C2 hydrocarbons separation.It is of great importance to develop selective and stable metal catalysts for the aqueous levulinic acid hydrogenation, yet challenging. Herein, we report a yolk-structured sing atom catalyst (SAC) with amine-modified Ru1/Fe3O4 core and periodic mesoporousorganosilica (PMO) shell, synthesized by a core-shell dual stabilization strategy. The Ru single atoms (0.76 wt%) are inserted into the oxygen va