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These results are consistent with the notion that reaction products that result from DMSO reacting with MA+ in the precursor solution are responsible for the formation of gap states.The present study involves an ecofriendly strategy for the reduction of bulk silver into its nanoforms by using the aqueous extracts of Mentha longifolia leaves (MLL), M. longifolia branches (ML, and Mentha arvensis (MA). Synthesis of silver nanoparticles (AgNPs) was confirmed initially by observing a change in the color of the reaction mixture followed by m