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The model results suggest As-hazard potential in yet-undetected areas. Our model performed well in predicting groundwater arsenic, with accuracy 82% and 84%; area under the curve (AUC) 0.89 and 0.88 for test data and validation datasets. An estimated ~90 million people across India are found to be exposed to high groundwater As from field-observed data, with the five states with highest hazard are West Bengal (28 million), Bihar (21 million), Uttar Pradesh (15 million), Assam (8.6 million) and Punjab (6 million). However it can be much