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As confirmed by both experimental and theoretical investigations, the vacancy-introduced NbP (V-NbP) exhibited fast transmembrane ion migration and high ionic selectivity originating from the improved electrostatic affinity of cations. When used in an all-natural lake water|seawater osmotic power generator, the macroscopic-scale V-NbP membrane delivered a record-high energy thickness of 10.7 W m-2, far exceeding the commercial standard of 5.0 W m-2. This work endo
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