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Although static electric fields have been effective in controlling ice nucleation, the highest freezing temperature (Tf) of water that can be achieved in an electric field (E) is still uncertain. We performed a systematic study of the effect of an electric field on water freezing by varying the thickness of a dielectric layer and the voltage across it in an electrowetting system. Results show that Tf first increases sharply with E and then reaches saturation at -3.5 °C after a critical value E of 6 × 106 V/m. Using classical heterogeneous