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Herein, the recent progress of MoxC on photocatalytic H2 evolution is assessed. Firstly, the preparation methods including chemical vapor deposition, temperature programming, and organic-inorganic hybridization are detailly summarized. Then, the essential structure, electronic properties, and particular conductance of MoxC tend to be illustrated to illuminate the advantages of MoxC as a co-catalyst for H2 development. Moreover, the different heterojunctions formed between MoxC as wel