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In this value, the priority is to identify the fly ash properties and also to give consideration to its prospective as natural material into the obtaining of high-value products. The physico-chemical and architectural qualities regarding the fly ash coming from different worldwide energy plants are quickly provided. The fly ash was sampled from energy plants where in actuality the burning of lignite and hard coal in pulverized-fuel boilers (PC) and circulating fluidized bed (CF boilers was used. T