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For both types of substrates considered in this work, pillared and porous with a reservoir, there is always an amount of reminiscent oil on the droplet, which is not absorbed by the substrate due to the interaction with the water and the gas. Both theoretical and numerical models can be easily modified to analyze other types of substrates and liquids.Using first-principles density functional theory calculations, we made an accurate structural characterization of the C60 superstructures self-assembled on the Tl-adsorbed Si(111) and Ge(1