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Superior material properties have been recently exhibited under the concept of biomimetic designs, where the material architectures are inspired by nature. In this study, a computational framework is developed to present novel architectured bi-material structures with tunable stiffness, strength, and toughness to be used for additive manufacturing (AM). The structure of natural nacre is mimicked to design robust multilayered structures constructed from hexagonal brittle and hard building blocks bonded with soft materials and supports. A