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Understanding the geochemical behaviour of the RN in the U-decay series is important for predicting and managing the risks associated with RN in both environmental (acid-mine drainage) and engineered (metallurgical extraction) processes. Effective modelling of long-term RN behaviour should incorporate this strong relative fractionation caused by contrasting geochemical behaviour of individual RN during and after their release into the water from uraninite and subsequent interaction with the surrounding aquifer host rocks.Bismuth oxyiod