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dwater. In most investigations of adsorption process, the effects of adsorbate properties on adsorption capacity were often not obtain enough attention, compared with the properties of adsorbent. Apart from the polarity, and the boiling point of adsorbate, the molecular space conformation is also play an important role in its adsorption behavior on porous materials. In this work, two series of orientation-designed activated carbon were used to study the microscopic adsorption behavior of amphiphilic propylene glycol methyl ether (PM)