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Magnetic porous water hyacinth-derived biochar (MPBCMW3) was synthesized via two-step Microwave (MW)-assisted processes. Characterization results not only testified high specific surface area (2097.50 m2/g) of the MPBCMW3 assisted by MW-assisted pyrolysis, but also revealed its favorable magnetism derived from MW-assisted hydrothermal process. The MPBCMW3 possessed pH-dependent monolayer adsorption capacities of 202.61 and 202.62 mg/g for Cr(VI) and TC with quick attainments of uptake equilibrium within 150 and 200 min. Moreover, the C