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More specifically, the Si6 unit in 2 is an unprecedented distorted silsesquioxane skeleton consisting of two condensed tetramembered rings. Structural features of compounds 1-3 were established by single crystal X-ray diffraction. Compound 2 was found to catalyze the oxidation of cyclohexane to cyclohexanol and cyclohexanone with H2O2 (a mixture of these products was obtained after adding PPh3 to the reaction solution) as well as the transformation of cyclohexanol to cyclohexanone under the action of tert-butyl hydroperoxide.Meayamycin B
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